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Liquid Bio-fuels - Ethanol

Ethanol (or ethly alcohol) is a flammable, colourless and slightly toxic liquid chemical compound consisting of oxygen, hydrogen and carbon. It has been used widely as a constituent of alcoholic beverages, flavourings, colourings and medicines as well as constituent of body scents and body/hair creams.  Ethanol has also found use as fuel in equipment and vehicle engines, because it is a clean burning fuel.

 

Ethanol is produced in two ways: 

  • Ethylene hydration; and

  • Biological fermentation of sugar or converted starch

Commercial alcohol is produced from ethylene hydration while ethanol biofuel is made from the fermentation of sugar or converted starch contained in grains and other agricultural products. Ethanol biofuel has been made from corn and wheat. This development has been initially thought of as good in that it increases

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Ethanol Feedstocks

Biodiesel Feedstocks

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demand for farmer's products and provides increased employment opportunities. However, it has been argued that fuel production from agricultural crops reduces the amount of such crops available for feeding. Consequently, to avoid dependence on food-based feedstocks, researches are continuously being conducted to identify new feedstocks (plants) that are dedicatedly planted for fuel production. Some of the plants that are planted specifically for the generation of ethanol and methanol, include: switchgrass, hemp, hybrid willow, hybrid poplar (cottonwoods) and sugarcane.

 

Ethanol is blended with gasoline to produce a fuel called "gasohol". Gasohol can be used in gasoline-powered vehicles manufactured since the 1980's. Similar to Biodiesel blend, ethanol blend is represented as Exx, where xx is the percentage of the ethanol in the gasohol. For instance, a 10% ethanol to 90 % gasoline blend is represented as E10; 15% ethanol to 85% gasoline blend as E15 etc.

Most gasoline-powered vehicles can run on a E10 blend. This blend is already available in several service stations in North America. Some vehicles are specially manufactured to operate on an E85 ethanol blend. The 15 percent gasoline is needed to assist in engine starting because pure ethanol is difficult to ignite in cold weather. This E-85 blend cannot be used in standard gasoline vehicles, however vehicles designed to run with a high ethanol blend can also operate using gasoline when necessary.

Ethanol burns more cleanly and completely than gasoline or diesel fuel. Gasohol seems to have slightly lower energy than gasoline which is compensated for by its higher combustion efficiency. E10 blend can be used directly in gasoline engines to produce same level of service without modifications to the gasoline engine. For higher blends (e.g. E85), larger petroleum tanks are designed and larger quantity of gasohol is required to produce similar service levels as the gasoline fuel.

Ethanol is renewable and is better for the environment. Though the conversion of biomass (feedstocks) produces GHG, on a Life Cycle basis, Ethanol reduces greenhouse gas (GHG) emissions. This is so because less emissions are produced during gasohol usage and the plants used to produce the ethanol served as carbon sink during their days of growing. Modifications are needed to an engine's intake valves, fuel-injection system and ignition system. Certain vehicle components must be made of alcohol-resistant materials (zinc, lead, magnesium, aluminum and certain plastics and rubbers that are commonly used in certain vehicles can be broken down by alcohol). For example, flex-fuel vehicles require stainless steel storage tanks and fuel lines. To overcome the problem of lower energy content, manufacturers have equipped E-85 vehicles with larger fuel tanks.

Ethanol is produced in large heated tanks called digesters. Plant materials and chemicals or yeasts are added to the digester. The process converts cellulose in the plant materials into sugars and then the sugars are converted into alcohol through fermentation.

Other resources:

 

 

 

Ethanol.org and Natural Resources Canada – Energy Sector

 




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