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Characteristics of Greenhouse Gases
The main greenhouse gases defined within
the context of the Kyoto Protocol are:
-
Carbon
Dioxide (CO2);
-
Methane
(CH4);
-
Nitrous
Oxide (N2O);
-
Hydrofluorocarbons (HFCs);
-
Perfluorocarbons (PFCs); and
-
Sulphur
Hexafluoride (SF6)
These gases are called greenhouse gases
because they produce greenhouse effects (refer to
Greenhouse Gases).
The major atmospheric constituents (nitrogen,
N2 and
oxygen, O2) are not greenhouse gases. This is because
homonuclear diatomic molecules such as N2 and O2
neither absorb nor emit infrared
radiation, as there is no net change in the
dipole moment of these molecules.
Water Vapour is a natural greenhouse
gas and is responsible for about 36-70% of the greenhouse effect on Earth.
Carbon dioxide results from both
natural and human sources and causes about the 9-26% of the greenhouse
effect. Human CO2 emissions are thought to come from burning of fossil
fuels for energy supply for such things as manufacturing engines,
lautomobiles, aviation industries etc, and from deforestation.
Methane gas results from industrial
activities as well as from landfill operations, agricultural activities
etc. Methane is believed to provide close to 4-9% greenhouse effect of the
atmosphere.
The percentage of the GHGs has been
increasing since the start of industrial revolution in 1750. This is
demonstrated by the Intergovernmental Panel on Climate Change (IPCC) list of greenhouse gases
shown below. IPCC
was established in 1988 by the
World Meteorological Organization (WMO) and the
United Nations Environment Programme (UNEP) to assess the "risk of
human-induced
climate change".
GHGs &
Concentration Changes Post-Industrial Revolution (1750) (Source: IPCC)
|
Gas |
Formula |
1998 Level |
Increase since 1750 |
|
Carbon dioxide |
(CO2) |
365ppm |
87 ppm |
| Methane |
(CH4) |
1,745ppb |
1,045ppb |
|
Nitrous oxide |
(N2O) |
314ppb |
44ppb |
|
Tetrafluoromethane |
(CF4) |
80ppt |
40ppt |
|
Hexafluoroethane |
(C2F6) |
3 ppt |
3ppt |
|
Sulfur hexafluoride |
(SF6) |
4.2ppt |
4.2ppt |
|
HFC-23* |
(CHF3) |
14ppt |
14ppt |
|
HFC-134a* |
(C2H2F4) |
7.5ppt |
7.5ppt |
|
HFC-152a* |
(C2H4F2) |
0.5ppt |
0.5ppt |
|
Dihydrogen monoxide |
(H2O) |
Unknown |
Unknown |
|